QuickLinks -- Click here to rapidly navigate through this document

Exhibit 5.1

May 1, 2007

Huntsman International LLC
500 Huntsman Way
Salt Lake City, UT 84108

Ladies and Gentlemen:

        Reference is made to the Registration Statement (the "Registration Statement") on Form S-4 (File No. 333-142207) filed by Huntsman International LLC, a Delaware limited liability company (the "Company"), with the Securities and Exchange Commission (the "Commission") on April 18, 2007 in connection with the registration by the Company under the Securities Act of 1933, as amended (the "Securities Act"), of the offer and exchange by the Company (the "Exchange Offer") of up to $175,000,000 aggregate principal amount of the Company's 7.375% Senior Subordinated Notes due 2015, €135,000,000 aggregate principal amount of its 7.5% Senior Subordinated Notes due 2015 and $347,000,000 aggregate principal amount of the Company's 7.875% Senior Subordinated Notes due 2014 to be registered under the Securities Act (collectively, the "New Notes"), which New Notes will be guaranteed by each of the guarantors named in Schedule I hereto (the "Note Guarantors"), for a like principal amount of the Company's outstanding 7.375% Senior Subordinated Notes due 2015, 7.5% Senior Subordinated Notes due 2015 and 7.875% Senior Subordinated Notes due 2014 (collectively, the "Old Notes"), which Old Notes have also been guaranteed by the Note Guarantors.

        In connection with the preparation of this opinion letter and as the basis for the opinions (the "Opinions") set forth below, we have made such investigations of the laws of the State of Utah, the laws of the State of New York, the DGCL (as defined below) and the DLLCA (as defined below) as we have deemed relevant and necessary, and we have examined such documents and records as we have deemed relevant and necessary, including the following:


        For purposes of this opinion letter, the following terms and phrases have the following meanings:

        With respect to the Opinions, we have relied solely upon the opinions of (i) Vinson & Elkins L.L.P., Houston, Texas, as special counsel to Huntsman Ethyleneamines Ltd., a Texas limited

2


partnership, Huntsman Fuels, L.P., a Texas limited Partnership, Huntsman International Fuels, L.P., a Texas limited partnership, Huntsman International Services Corporation, a Texas corporation, Huntsman Propylene Oxide Ltd., a Texas limited partnership, and Tioxide Group, an unlimited company organized under the laws of England (collectively, the "Texas and U.K. Guarantors"), and (ii) Walkers, as special counsel to Tioxide Americas Inc., a corporation incorporated under the laws of the Cayman Islands (the "Cayman Guarantor"), in each case, dated the date hereof, a copy of each of which is being filed as an exhibit to the Registration Statement, as to matters of the laws of the State of Texas, England and the Cayman Islands, respectively, with respect to each of (x) the Texas and U.K. Guarantors and the Cayman Guarantor being duly incorporated or organized, validly existing and in good standing under the laws of its respective jurisdiction of organization or incorporation, (y) the Texas and U.K. Guarantors and the Cayman Guarantor having the corporate, limited partnership or limited liability company power and authority, as applicable, to execute, deliver and perform its respective obligations under the Indentures and its respective Guarantees and (z) the Indentures being duly executed by the Texas and U.K. Guarantors and the Cayman Guarantor having duly authorized and executed the Indentures and its respective Guarantees, in each case, as set forth in such opinions.

        Based upon the examination described above, subject to the assumptions, qualifications, limitations and exceptions set forth in this opinion letter and under current interpretations of the laws of the State of Utah, the laws of the State of New York, the DGCL and the DLLCA, we are of the opinion that:

        1.     The Company and each limited liability company Note Guarantor organized under the laws of the State of Delaware has been duly formed and is validly existing as a limited liability company in good standing under the laws of the State of Delaware.

        2.     Each limited liability company Note Guarantor organized under the laws of the State of Utah has been duly formed and is validly existing as a limited liability company in good standing under the laws of the State of Utah.

        3.     Each corporate Note Guarantor incorporated under the laws of the State of Utah has been duly formed and is validly existing as a corporation in good standing under the laws of the State of Utah.

        4.     Each corporate Note Guarantor incorporated under the laws of the State of Delaware has been duly formed and is validly existing as a corporation in good standing under the laws of the State of Delaware.

        5.     The Company, each limited liability company Note Guarantor organized under the laws of the State of Delaware and each limited liability company Note Guarantor organized under the laws of the State of Utah has the limited liability company power and the limited liability company authority to execute and deliver the Indentures and to perform its respective obligations thereunder (including in the case of such Note Guarantors, the guarantee of the New Notes pursuant to the Indentures); and the limited liability company action required to be taken by the Company, each limited liability company Note Guarantor organized under the laws of the State of Utah and each limited liability company Note Guarantor organized under the laws of the State of Delaware for the due authorization, execution and delivery of the Indentures and the consummation by it of the transactions contemplated thereby (including in the case of such Note Guarantors, the guarantee of the New Notes pursuant to the Indentures) has been duly and validly taken.

        6.     Each corporate Note Guarantor incorporated under the laws of the State of Utah and each corporate Note Guarantor incorporated under the laws of the State of Delaware has the corporate power and corporate authority to execute and deliver the Indentures and to perform its respective obligations thereunder (including the guarantee of the New Notes pursuant to the Indentures); and the corporate action required to be taken by each corporate Note Guarantor incorporated under the laws of the State of Utah and each corporate Note Guarantor incorporated under the laws of the State of

3



Delaware for the due authorization, execution and delivery of the Indentures and the consummation by it of the transactions contemplated thereby (including the guarantee of the New Notes pursuant to the Indentures) has been duly and validly taken.

        7.     The Indentures have been duly authorized, executed and delivered by the Company, each Note Guarantor incorporated or organized under the laws of the State of Utah and each Note Guarantor incorporated or organized under the laws of the State of Delaware.

        8.     When the New Notes have been duly executed, authenticated and delivered in accordance with the Indentures in exchange for the Old Notes in accordance with the Indentures and the Exchange Offer, the New Notes will be legally valid and binding obligations of the Company, enforceable against the Company in accordance with their terms, except as may be limited by bankruptcy, insolvency, reorganization, moratorium or similar laws relating to or affecting creditors' rights generally (including, without limitation, fraudulent conveyance laws), and by general principles of equity including, without limitation, concepts of materiality, reasonableness, good faith and fair dealing and the possible unavailability of specific performance or injunctive relief, regardless of whether considered in a proceeding in equity or at law.

        9.     When the New Notes have been duly executed, authenticated and delivered in accordance with the Indentures in exchange for the Old Notes in accordance with the Indentures and the Exchange Offer, the Guarantees of the Note Guarantors will be the legally valid and binding obligations of the Note Guarantors, enforceable against the Note Guarantors in accordance with their terms, except as may be limited by bankruptcy, insolvency, reorganization, moratorium or similar laws relating to or affecting creditors' rights generally (including, without limitation, fraudulent conveyance laws), and by general principles of equity including, without limitation, concepts of materiality, reasonableness, good faith and fair dealing and the possible unavailability of specific performance or injunctive relief, regardless of whether considered in a proceeding in equity or at law.

        The Opinions are predicated upon and are limited by the matters set forth in the Opinions and are further subject to the qualifications, exceptions, assumptions and limitations set forth below:

        A.    The Opinions are limited to the laws of the State of Utah, the laws of the State of New York, the DGCL and the DLLCA. We express no opinion as to local laws or the laws of any other state or country.

        B.    In rendering the Opinions, we have assumed that each of the Company, each Note Guarantor organized under the laws of the State of Delaware and each Note Guarantor organized under the laws of the State of Utah has complied with the provisions of the securities laws, "blue sky" laws, securities regulations, and/or securities rules of any applicable state and the United States of America.

        C.    The Opinions that relate to specific agreements or documents, relate to the specified agreements or documents, and do not extend to documents, agreements or instruments referred to in such agreements or documents (even if incorporated therein by reference), or to any exhibits, annexes or schedules that are not expressly identified in this opinion letter as having been examined by us.

        D.    In rendering the Opinions, we have assumed (i) the genuineness of all signatures, (ii) the capacity and the authority of all individuals executing documents (other than officers of the Company, the Note Guarantors organized under the laws of the State of Delaware and the Note Guarantors organized under the laws of the State of Utah), (iii) the conformity to the original documents of all photocopies or facsimile copies submitted to us, whether certified or not, (iv) the authenticity of all documents submitted to us as originals, and (v) the conformity, in all material respects, of all copies of the Indentures to the copy of the Indentures examined by us.

        E.    The Opinions are limited to those expressly stated and no other opinions should be implied.

4



        F.     Unless otherwise specifically indicated, the Opinions are as of the date of this opinion letter and we assume no obligation to update or supplement the Opinions to reflect any facts or circumstances that may later come to our attention or any change in the law that may occur after the date of this opinion letter.

        We hereby consent to the use of this opinion as an exhibit to the Registration Statement. In giving this consent, we do not thereby admit that we are included in the category of persons whose consent is required under Section 7 of the Securities Act or the rules and regulations promulgated thereunder.

5



Schedule I

Name of Guarantor

  Jurisdiction of
Incorporation/Organization

Airstar Corporation   Utah
Eurofuels LLC   Delaware
Eurostar Industries LLC   Delaware
Huntsman Australia Inc.    Utah
Huntsman Advanced Materials Americas Inc.    Delaware
Huntsman Advanced Materials Holdings LLC   Delaware
Huntsman Advanced Materials LLC   Delaware
Huntsman Chemical Company LLC   Utah
Huntsman Chemical Finance Corporation   Utah
Huntsman Chemical Purchasing Corporation   Utah
Huntsman EA Holdings LLC   Delaware
Huntsman Enterprises, Inc.    Utah
Huntsman Ethyleneamines Ltd.    Texas
Huntsman Expandable Polymers Company, LC   Utah
Huntsman Family Corporation   Utah
Huntsman Fuels, L.P.    Texas
Huntsman Group Holdings Finance Corporation   Utah
Huntsman Group Intellectual Property Holdings Corporation   Utah
Huntsman Headquarters Corporation   Utah
Huntsman International Chemicals Corporation   Utah
Huntsman International Financial LLC   Delaware
Huntsman International Fuels, L.P.    Texas
Huntsman International Services Corporation   Texas
Huntsman International Trading Corporation   Delaware
Huntsman MA Investment Corporation   Utah
Huntsman MA Services Corporation   Utah
Huntsman Petrochemical Canada Holdings Corporation   Utah
Huntsman Petrochemical Corporation   Delaware
Huntsman Petrochemical Finance Corporation   Utah
Huntsman Petrochemical Purchasing Corporation   Utah
Huntsman Polymers Corporation   Delaware
Huntsman Polymers Holdings Corporation   Utah
Huntsman Procurement Corporation   Utah
Huntsman Propylene Oxide Holdings LLC   Delaware
Huntsman Propylene Oxide Ltd.    Texas
Huntsman Purchasing, Ltd.    Utah
Huntsman Texas Holdings LLC   Delaware
JK Holdings Corporation   Delaware
Petrostar Fuels LLC   Delaware
Petrostar Industries LLC   Delaware
Polymer Materials Inc.    Utah
Tioxide Americas Inc.    Cayman Islands
Tioxide Group   U.K.

6




QuickLinks

Schedule I